Stereocontrolled Synthesis of Novel Spirocyclic Oxa-Bridged Cyclooctanoids through Sequential Transformations of Pentafulvenes

Radhakrishnan, K. ; Krishnan, K. ; Kuthanappillil, Jinesh ; John, Jubi ; Suresh, C. ; Suresh, E. (2008) Stereocontrolled Synthesis of Novel Spirocyclic Oxa-Bridged Cyclooctanoids through Sequential Transformations of Pentafulvenes Synthesis, 2008 (13). pp. 2134-2140. ISSN 0039-7881

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Official URL: http://doi.org/10.1055/s-2008-1067124

Related URL: http://dx.doi.org/10.1055/s-2008-1067124

Abstract

A novel and efficient methodology for the stereocontrolled synthesis of spirocyclic oxa-bridged cyclooctanoids having multiple spiro centers is described. The cycloaddition reaction, which affords spirocyclic cyclooctanoids is highly sterospecific and has been supported by theoretical calculations.

Item Type:Article
Source:Copyright of this article belongs to Georg Thieme Verlag KG
Keywords:pentafulvenes - oxidopyrylium betaines - oxa-bridged spirocycles - macromolecules
ID Code:127519
Deposited On:13 Oct 2022 10:51
Last Modified:13 Oct 2022 10:51

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