Madhu, Meera ; Ramakrishnan, Remya ; Vijay, Vishnu ; Hariharan, Mahesh (2021) Free Charge Carriers in Homo-Sorted π-Stacks of Donor–Acceptor Conjugates Chemical Reviews, 121 (13). pp. 8234-8284. ISSN 0009-2665
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Official URL: http://doi.org/10.1021/acs.chemrev.1c00078
Related URL: http://dx.doi.org/10.1021/acs.chemrev.1c00078
Abstract
Inspired by the high photoconversion efficiency observed in natural light-harvesting systems, the hierarchical organization of molecular building blocks has gained impetus in the past few decades. Particularly, the molecular arrangement and packing in the active layer of organic solar cells (OSCs) have garnered significant attention due to the decisive role of the nature of donor/acceptor (D/A) heterojunctions in charge carrier generation and ultimately the power conversion efficiency. This review focuses on the recent developments in emergent optoelectronic properties exhibited by self-sorted donor-on-donor/acceptor-on-acceptor arrangement of covalently linked D–A systems, highlighting the ultrafast excited state dynamics of charge transfer and transport. Segregated organization of donors and acceptors promotes the delocalization of photoinduced charges among the stacks, engendering an enhanced charge separation lifetime and percolation pathways with ambipolar conductivity and charge carrier yield. Covalently linking donors and acceptors ensure a sufficient D–A interface and interchromophoric electronic coupling as required for faster charge separation while providing better control over their supramolecular assemblies. The design strategies to attain D–A conjugate assemblies with optimal charge carrier generation efficiency, the scope of their application compared to state-of-the-art OSCs, current challenges, and future opportunities are discussed in the review. An integrated overview of rational design approaches derived from the comprehension of underlying photoinduced processes can pave the way toward superior optoelectronic devices and bring in new possibilities to the avenue of functional supramolecular architectures.
Item Type: | Article |
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Source: | Copyright of this article belongs to ResearchGate GmbH. |
ID Code: | 127020 |
Deposited On: | 17 Oct 2022 05:22 |
Last Modified: | 09 Nov 2022 07:50 |
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