Reactions of dimethyl acetylenedicarboxylate-I reactions with phenacylanilines, ethyl anthranilate and aniline

Khetan, S. K. ; Hiriyakkanavar, J. G. ; George, Manapurathu Verghese (1968) Reactions of dimethyl acetylenedicarboxylate-I reactions with phenacylanilines, ethyl anthranilate and aniline Tetrahedron, 24 (4). pp. 1567-1575. ISSN 0040-4020

Full text not available from this repository.

Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)82463-7

Abstract

Dimethyl acetylendicarboxylate reacts with phenacylanilines to give Michael adducts, which undergo cyclization to pyrrole derivatives. Similarly, ethyl anthranilate and aniline react with dimethyl acetylenedicarboxylate giving rise to the corresponding fumarates which undergo cyclization under pyrolytic conditions to give 8-carbethoxy-2-carbomethoxy-4(1H)-quinolone and α-anilino-N-phenyl-maleimide, respectively.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:12685
Deposited On:11 Nov 2010 09:12
Last Modified:14 Feb 2011 08:58

Repository Staff Only: item control page