Ghosh, Tridev ; Jana, Snehasish ; Dash, Jyotirmayee (2019) KOtBu-Promoted Transition-Metal-Free Transamidation of Primary and Tertiary Amides with Amines Organic Letters, 21 (17). pp. 6690-6694. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/acs.orglett.9b02306
Related URL: http://dx.doi.org/10.1021/acs.orglett.9b02306
Abstract
This work discloses transamidation of primary and tertiary amides with a range of aryl, heteroaryl, and aliphatic amines using potassium tert-butoxide. The reaction proceeds at room temperature under transition-metal-free conditions providing secondary amides in high yields. Moreover, reaction of cyclopropyl amine with tertiary amides proceeds with ring-opening to provide a rapid access to enamides.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier B.V. |
| ID Code: | 126655 |
| Deposited On: | 17 Oct 2022 05:43 |
| Last Modified: | 17 Oct 2022 05:43 |
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