Khan, F A ; Dash, J ; B, Prabhudas ; N, Sahu (2001) Synthesis of Novel Caged Bishemiacetals and their Facile Conversion to Symmetric Bis-α-halo-γ-lactones Journal of the Indian Institute of Sciences (81). pp. 325-331. ISSN 0970-4140
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Abstract
A highly efficient method for the construction of novel bis-α-halo-γ-lactones (4a,b) via oxidative cleavage of caged bishemiacetals (9a,b) has been developed. Furthermore, a new base-catalyzed cleavage of diketo diacetate (8b) leading to the formation of α-monobromo-bis-γ-lactone (10) and the synthesis of bis-γ-lactone (11) are described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Institute of Sciences |
| Keywords: | Bis-hemiacetals; γ-lactones; α-diketones; Tetrahalonorbornenes |
| ID Code: | 126444 |
| Deposited On: | 17 Oct 2022 05:58 |
| Last Modified: | 17 Oct 2022 05:58 |
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