Redox, ionic strength, and pH sensitive supramolecular polymer assemblies

Ghosh, Suhrit ; Yesilyurt, Volkan ; Savariar, Elamprakash N. ; Irvin, Katharine ; Thayumanavan, S. (2009) Redox, ionic strength, and pH sensitive supramolecular polymer assemblies Journal of Polymer Science Part A: Polymer Chemistry, 47 (4). pp. 1052-1060. ISSN 0887-624X

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Official URL: http://doi.org/10.1002/pola.23204

Related URL: http://dx.doi.org/10.1002/pola.23204

Abstract

Formation of micelle-type assembly from supramolecular complexation of a surfactant and an oppositely charged homopolymer is demonstrated. The lower CAC observed for these assemblies suggest that the electrostatic interaction provides an amphiphilic homopolymer-like structure. The stimulus-induced disassembly of these supramolecular structures has been accomplished with variations in redox characteristics, ionic strength, and pH of the medium. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1052–1060, 2009

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