Small-Molecule-Induced Folding of a Synthetic Polymer

Ghosh, Suhrit ; Ramakrishnan, S. (2005) Small-Molecule-Induced Folding of a Synthetic Polymer Angewandte Chemie International Edition, 44 (34). pp. 5441-5447. ISSN 1433-7851

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Official URL: http://doi.org/10.1002/anie.200501448

Related URL: http://dx.doi.org/10.1002/anie.200501448

Abstract

Stack 'em high: A polyimide with pyromellitic diimide units linked by hexaoxyethylene segments can be made to fold by cooperative two-point interactions on addition of a folding agent (see scheme). The ammonium group of the folding agent forms complexes with the oxyethylene spacer which greatly facilitates the formation of charge-transfer complexes between the aromatic units of the two components.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society
ID Code:126254
Deposited On:17 Oct 2022 11:44
Last Modified:17 Oct 2022 11:44

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