Walia, Preet Kamal ; Sharma, Manik ; Kumar, Manoj ; Bhalla, Vandana (2019) UV light promoted ‘Metal’/‘Additive’-free oxidation of alcohols: investigating the role of alcohols as electron donors RSC Advances, 9 (62). pp. 36198-36203. ISSN 2046-2069
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Official URL: http://doi.org/10.1039/C9RA06490G
Related URL: http://dx.doi.org/10.1039/C9RA06490G
Abstract
UV light promoted selective oxidation of primary and secondary alcohols has been demonstrated under ‘metal-free’ and ‘additive-free’ conditions. Under the optimized conditions, a variety of aromatic, heteroaromatic, and alicyclic alcohols have been examined for their transformations to the corresponding carbonyl compounds. The mechanistic studies emphasize the important role of substrate (alcohol) and solvent (DMSO) in the generation of superoxide radical which is a vital intermediate for the transformation. This study also highlights the role of air as the oxidant in the oxidation process. Further, the practical application of the strategy has also been demonstrated for the oxidation of the alcoholic moiety in cholesterol.
Item Type: | Article |
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Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
ID Code: | 125475 |
Deposited On: | 08 Feb 2022 08:27 |
Last Modified: | 08 Feb 2022 08:27 |
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