Kaur, Lovjot ; Deol, Harnimarta ; Kumar, Manoj ; Bhalla, Vandana (2020) Integrating CuO−Fe 2 O 3 Nanocomposites and Supramolecular Assemblies of Phenazine for Visible‐Light Photoredox Catalysis Chemistry – An Asian Journal, 15 (6). pp. 892-898. ISSN 1861-4728
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Official URL: http://doi.org/10.1002/asia.201901687
Related URL: http://dx.doi.org/10.1002/asia.201901687
Abstract
A photoredox catalytic ensemble consisting of CuO-Fe2O3 nanocomposites and oligomeric derivative of phenazine has been developed. The prepared system acts as an efficient photoredox catalyst for C−N bond formation reaction via SET mechanism under ‘green’ conditions (aerial environment, mixed aqueous media, recyclable), requiring less equivalents of base and amine substrate. The present study demonstrates the significant role of supramolecular assemblies as photooxidants and reductants upon irradiation and their important contribution towards the activation of the metallic centre through energy transfer and electron transfer pathways. The potential of oligomer 4: CuO-Fe2O3 has also been explored for C−C bond formation reactions via the Sonogashira protocol.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 125473 |
| Deposited On: | 08 Feb 2022 08:27 |
| Last Modified: | 08 Feb 2022 08:27 |
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