Sureshbabu, Bemineni ; Ramkumar, Venkatachalam ; Sankararaman, Sethuraman (2014) Facile base-free in situ generation and palladation of mesoionic and normal N-heterocyclic carbenes at ambient conditions Dalton Transactions, 43 (28). pp. 10710-10712. ISSN 1477-9226
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Official URL: http://doi.org/10.1039/c4dt01112k
Related URL: http://dx.doi.org/10.1039/c4dt01112k
Abstract
Synthesis of normal and mesoionic N-heterocyclic carbene Pd(II) complexes in near quantitative yields from the corresponding NHC precursor salts under base free and ambient conditions is reported. A plausible mechanism involving charge-assisted hydrogen bonded intermediates is proposed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
| ID Code: | 124319 |
| Deposited On: | 12 Nov 2021 12:27 |
| Last Modified: | 12 Nov 2021 12:27 |
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