Mir, Bilal Ahmad ; Rajamanickam, Suresh ; Begum, Pakiza ; Patel, Bhisma K. (2020) tert -Butyl Nitrite Mediated Nitro-Nitratosation of Internal Alkenes European Journal of Organic Chemistry, 2020 (17). pp. 2617-2625. ISSN 1434-193X
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Official URL: http://doi.org/10.1002/ejoc.202000149
Related URL: http://dx.doi.org/10.1002/ejoc.202000149
Abstract
In an oxygen atmosphere tert-butyl nitrite (TBN) reacts with unsymmetrical internal benzylic alkenes to give nitro-nitratosation product whereas α,β-unsaturated carboxylic acid provides nitroalkene. In both cases the NO2 group attacks only to the β-carbon, even though other radical co-exists in the medium.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 124215 |
| Deposited On: | 08 Nov 2021 12:11 |
| Last Modified: | 08 Nov 2021 12:11 |
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