Adalikwu, Stephen Adie ; Mothika, Venkata Suresh ; Hazra, Arpan ; Maji, Tapas Kumar (2019) Polar functional groups anchored to a 2D MOF template for the stabilization of Pd(0) nps for the catalytic C–C coupling reaction Dalton Transactions, 48 (21). pp. 7117-7121. ISSN 1477-9226
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Official URL: http://doi.org/10.1039/C8DT04766A
Related URL: http://dx.doi.org/10.1039/C8DT04766A
Abstract
A 2D porous MOF, {[Cu(1,2,3-btc)(bpe)(H2O)]·H2O}n (1), has been synthesized using a mixed linker system. The structural determination showed non-coordinated carboxylate groups decorating the pore surface. The desolvated MOF (1a) with pendant carboxylate groups was used as a template for the stabilization of Pd nps (2–3 nm) and the resulting composite Pd(0)@1a showed efficient catalytic activity for the Suzuki–Miyaura C–C coupling reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
| ID Code: | 124020 |
| Deposited On: | 29 Oct 2021 09:50 |
| Last Modified: | 29 Oct 2021 09:50 |
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