Ayyappan, Ramaraj ; Coppel, Yannick ; Vendier, Laure ; Ghosh, Sundargopal ; Sabo-Etienne, Sylviane ; Bontemps, Sébastien (2021) Synthesis and reactivity of phosphine borohydride compounds Chemical Communications, 57 (3). pp. 375-378. ISSN 1359-7345
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Official URL: https://pubs.rsc.org/en/journals/journalissues/cc#...
Related URL: http://dx.doi.org/10.1039/D0CC07072F
Abstract
Four lithium phosphine borohydride compounds featuring phenyl and naphthyl linkers have been synthesized. In-depth NMR analysis affords evidence for non-bonded through space P–B coupling. Reactivity towards CO2 leads to LiH transfer and to the quantitative formation of the corresponding ambiphilic phosphine–borane products.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 123750 |
| Deposited On: | 13 Oct 2021 05:38 |
| Last Modified: | 13 Oct 2021 05:38 |
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