Unprecedented copper(I)-catalyzed photochemical reaction of diethyl ether with vicinal diols and ketals

Mondal, Sujit ; Yadav, Ram Naresh ; Ghosh, Subrata (2010) Unprecedented copper(I)-catalyzed photochemical reaction of diethyl ether with vicinal diols and ketals Tetrahedron Letters, 51 (33). pp. 4452-4454. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.06.080

Abstract

A novel Cu(I)-catalyzed photochemical reaction of diethyl ether with vicinal diols and their ketals is reported. The most remarkable feature is the transformation of 1,2-diols and their ketals to acetals of acetaldehyde under totally neutral condition without using acetaldehyde.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Acetals; Photochemistry; Catalysis
ID Code:12372
Deposited On:10 Nov 2010 06:20
Last Modified:12 Feb 2011 10:24

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