Ghosh, Manju ; Bose, Sritama ; Maity, Soumitra ; Ghosh, Subrata (2009) Enantiodivergent synthesis of (-)-methylenolactocin and (+)-methylenolactocin from D-mannitol Tetrahedron Letters, 50 (50). pp. 7102-7104. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2009.10.011
Abstract
An enantiodivergent synthesis of both enantiomers of methylenolactocin is described through stereocontrolled addition of n-pentyl magnesium bromide to two D-mannitol-derived diastereomerically related aldehydes having an α-chiral center with a β hetero atom.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Anti-tumor Compounds; Asymmetric Synthesis; Lactone; Stereocontrol |
| ID Code: | 12359 |
| Deposited On: | 10 Nov 2010 06:23 |
| Last Modified: | 12 Feb 2011 10:34 |
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