Intramolecular [2+2] photocycloaddition of 1,6-dienes incorporated in a furanose ring. Unusual formation of cis-syn-cis 6-oxatricyclo[6.2.0.03,7]decanes

Ghosh, Subrata ; Banerjee, Shyamapada ; Chowdhury, Krishna ; Mukherjee, Monika ; Howard, Judith A. K. (2001) Intramolecular [2+2] photocycloaddition of 1,6-dienes incorporated in a furanose ring. Unusual formation of cis-syn-cis 6-oxatricyclo[6.2.0.03,7]decanes Tetrahedron Letters, 42 (34). pp. 5997-6000. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)01167-4

Abstract

Intramolecular [2+2] photocycloaddition of 1,6-dienes incorporated in a furanose ring either in the presence of a copper(I) catalyst or with a sensitiser led to the unusual formation of cis-syn-cis adducts.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Carbohydrates; Cycloaddition; Cyclobutanes; Photochemistry; Stereocontrol
ID Code:12316
Deposited On:10 Nov 2010 06:26
Last Modified:10 Nov 2010 06:26

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