Phase changes in Na1/2Pr1/2TiO3: A synchrotron X-ray powder diffraction study

Ranjan, Rajeev ; Boysen, Hans (2010) Phase changes in Na1/2Pr1/2TiO3: A synchrotron X-ray powder diffraction study Solid State Communications, 150 (25-26). pp. 1128-1131. ISSN 0038-1098

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Official URL: http://doi.org/10.1016/j.ssc.2010.03.024

Related URL: http://dx.doi.org/10.1016/j.ssc.2010.03.024

Abstract

A temperature dependent synchrotron X-ray powder diffraction study has been carried out on Na1/2Pr1/2TiO3 up to 850 °C. The compound shows orthorhombic (Pbnm) orthorhombic (Ibmm) tetragonal (I4/mcm) transitions at ∼150 °C, and ∼750 °C, respectively. An unusual volume expansion below 500 °C has been noticed in the Ibmm phase, suggesting the onset of another, yet unknown, physical phenomenon unrelated to the crystallographic changes below this temperature.

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Deposited On:02 Sep 2021 07:22
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