Maintaining local displacive disorders in Na0.5Bi0.5TiO3 piezoceramics by K0.5Bi0.5TiO3 substitution

Rao, Badari Narayana ; Senyshyn, Anatoliy ; Olivi, Luca ; Sathe, Vasant ; Ranjan, Rajeev (2016) Maintaining local displacive disorders in Na0.5Bi0.5TiO3 piezoceramics by K0.5Bi0.5TiO3 substitution Journal of the European Ceramic Society, 36 (8). pp. 1961-1972. ISSN 0955-2219

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Official URL: http://doi.org/10.1016/j.jeurceramsoc.2016.02.031

Related URL: http://dx.doi.org/10.1016/j.jeurceramsoc.2016.02.031

Abstract

A comprehensive global and local structural characterization using X-ray and neutron diffraction, and EXAFS have been performed to investigate the effect of electrical poling on the structure of (1−x)Na0.5Bi0.5TiO3–(x)K0.5Bi0.5TiO3 compositions. While the annealed samples showed definite indication of presence of local displacive disorders in all the compositions studied (0 < x < 0.3), this disorder persisted to some extent even after poling the samples. The tendency of electric field to reduce the local displacive disorder decreased with increasing K0.5Bi0.5TiO3 content in the samples.

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