Long-period modulated structure and electric-field-induced structural transformation in Na_0.5Bi_0.5TiO₃ -based lead-free piezoelectrics

Abstract

Na_0.5Bi_0.5TiO₃ - based lead-free piezoelectrics exhibiting giant piezostrain are technologically interesting materials for actuator applications. The lack of clarity with regard to the structure of the nonpolar phase of this system has hindered the understanding of the structural mechanism associated with the giant piezostrain and other related phenomena. In this paper, we have investigated the structure and field-induced phase transformation behavior of a model system ( 0.94−x) Na_0.5Bi_0.5TiO₃−0.06 BaTiO₃−xK_0.5Na_0.5NbO₃(0.0≤ x ≤ 0.025). A detailed structural analysis using neutron powder diffraction revealed that the nonpolar phase is neither cubic nor a mixture of rhombohedral (R3c) and tetragonal (P4bm) phases as commonly reported in literature but exhibits a long-period modulated structure, which is most probably of the type √2×√2×n with n=16 . Our results suggest that the giant piezoelectric strain is associated with a field-induced phase transformation of the long-period modulated structure to rhombohedral R 3 c structure above a critical field. We also demonstrate that the giant piezostrain is lost if the system retains a fraction of the field-induced R 3 c phase. A possible correlation among depolarization temperature, giant piezostrain, and its electrical fatigue behavior has also been indicated.