Large nonlinear electrostrain and piezoelectric response in nonergodic (Na,K)0.5Bi0.5TiO3 : Synergy of structural disorder and tetragonal phase in proximity to a morphotropic phase boundary

Abstract

Among the different piezoceramics, Na_0.5Bi_0.5TiO₃ (NBT)-based systems have the unique distinction of exhibiting very large electrostrain ( > 0.5 % ) when pushed at the threshold of ergodic–nonergodic relaxor transition. However, this strategy severely compromises the system's weak-signal piezoelectric response ( d 33 ). Here, we show that a similar level of electrostrain is feasible together with high d 33 by a different approach. In our approach, the system is kept well within the nonergodic relaxor regime close to an interferroelectric instability, and the inherent structural (tilt) disorder is exploited for large reverse switching of the ferroelastic domains in the field-stabilized ferroelectric phase. A synergy of this combination is demonstrated in ( 1 − x ) Na_0.5Bi_0.5TiO₃ − ( x ) K_0.5 Bi_0.5TiO₃ ; x = 0.25 which exhibit electrostrain of ∼0.6% and d 33 (∼210 pC/N). With the added advantage of high depolarization temperature ( T_d ∼ 185 ∘ C ) this piezoceramic stands unique for showing the best combination of the three most sought after properties.