Yadav, M. Ramu ; Rit, Raja K. ; Sahoo, Akhila K. (2013) Sulfoximine Directed Intermolecular o-C–H Amidation of Arenes with Sulfonyl Azides Organic Letters, 15 (7). pp. 1638-1641. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/ol400411v
Related URL: http://dx.doi.org/10.1021/ol400411v
Abstract
The Ru(II)-catalyzed intermolecular o-C–H amidation of arenes in N-benzoylated sulfoximine with sulfonyl azides is demonstrated. The reaction proceeds with broad substrate scope and tolerates various functional groups. Base hydrolysis of the amidation product provides the anthranilic acid derivatives and methylphenyl sulfoximine (MPS) directing group. This method is successfully employed for the synthesis of HMR 1766.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 122454 |
| Deposited On: | 02 Aug 2021 15:05 |
| Last Modified: | 02 Aug 2021 15:05 |
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