Synthesis of multicyclic pyrrolidines via copper(I) catalyzed photobicyclization of ethyl N,N-diallyl carbamates

Salomon, Robert G. ; Ghosh, Subrata ; Raychaudhuri, Swadesh R. ; Miranti, Thomas S. (1984) Synthesis of multicyclic pyrrolidines via copper(I) catalyzed photobicyclization of ethyl N,N-diallyl carbamates Tetrahedron Letters, 25 (30). pp. 3167-3170. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)90999-2

Abstract

Ultraviolet irradiation of ethyl N,N-diallylcarbamates in the presence of copper(I) trifluoromethanesulfonate (CuOTf) catalyst results in photobicyclization to give bi or tricyclic pyrrolidines incorporating the N-carboethoxy-3-azabicyclo [3.2.0] heptane moiety.

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