Schramm, Michael P. ; Reddy, D. Srinivasa ; Kozmin, Sergey A. (2001) Siloxyalkyne-Alkene Metathesis: Rapid Access to Highly Functionalized Enones Angewandte Chemie International Edition, 40 (22). pp. 4274-4277. ISSN 1433-7851
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Official URL: http://doi.org/10.1002/1521-3773(20011119)40:22<42...
Related URL: http://dx.doi.org/10.1002/1521-3773(20011119)40:22<4274::AID-ANIE4274>3.0.CO;2-#
Abstract
Mechanistically intriguing participation of siloxyalkynes occurs in the intramolecular Ru-catalyzed metathesis with terminal alkenes (see scheme; Ms=methanesulfonyl). Combined with efficient protodesilylation, this process resulted in the development of a new method for the synthesis of highly functionalized enones starting from readily accessible acyclic precursors. Heterocyclic and polycyclic compounds were prepared efficiently, which illustrates the generality of this novel method
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 122030 |
| Deposited On: | 27 Jul 2021 10:44 |
| Last Modified: | 30 Jul 2021 12:57 |
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