A General Approach Toward Bakkanes: Short Synthesis of (±)-Bakkenolide-A (Fukinanolide)†

Reddy, D. Srinivasa (2004) A General Approach Toward Bakkanes: Short Synthesis of (±)-Bakkenolide-A (Fukinanolide)† Organic Letters, 6 (19). pp. 3345-3347. ISSN 1523-7060

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Official URL: http://doi.org/10.1021/ol048726d

Related URL: http://dx.doi.org/10.1021/ol048726d

Abstract

An efficient, general, and fully stereocontrolled approach to the family of bakkanes is disclosed. This route highlights a highly diastereoselective Diels−Alder/aldol sequence to furnish the common hydrindane precursor for the synthesis of bakkanes. The projected common intermediate was transformed to the (±)-bakkenolide-A in a short sequence.

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ID Code:122025
Deposited On:27 Jul 2021 10:27
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