An Enantiospecific Route to (+)-(1R,3S)-cis-Chrysanthemic Acid from (-)-d-Pantolactone¹

Reddy, D. Srinivasa ; Hajare, Atul ; Datrange, Laxmikant ; Murthy, Y. ; Bhuniya, Debnath (2011) An Enantiospecific Route to (+)-(1R,3S)-cis-Chrysanthemic Acid from (-)-d-Pantolactone¹ Synthesis, 2011 (07). pp. 1067-1070. ISSN 0039-7881

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Official URL: http://doi.org/10.1055/s-0030-1258451

Related URL: http://dx.doi.org/10.1055/s-0030-1258451

Abstract

In this paper, a novel route for the synthesis of (+)-(1R,3S)-cis-chrysanthemic acid is described. The use of readily available (-)-D-pantolactone as a starting point, application of ring-closing metathesis to form the cyclopentene intermediate, and Haller-Bauer/Grob-type fragmentation to form the target compound are the highlights of the present synthesis.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers Inc
ID Code:122006
Deposited On:27 Jul 2021 09:04
Last Modified:02 Aug 2021 07:01

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