Zinc mediated allylations of chlorosilanes promoted by ultrasound: Synthesis of novel constrained sila amino acids

Ramesh, Remya ; Reddy, D. Srinivasa (2014) Zinc mediated allylations of chlorosilanes promoted by ultrasound: Synthesis of novel constrained sila amino acids Organic and Biomolecular Chemistry, 12 (24). pp. 4093-4097. ISSN 1477-0520

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Official URL: http://doi.org/10.1039/C4OB00294F

Related URL: http://dx.doi.org/10.1039/C4OB00294F

Abstract

A simple, fast and efficient method for allylation and propargylation of chlorosilanes through zinc mediation and ultrasound promotion is reported. As a direct application of the resulting bis-allylsilanes, three novel, constrained sila amino acids are prepared for the first time. The design and synthesis of the constrained sila analogue of GABA (γ-amino butyric acid) is a highlight of this work.

Item Type:Article
Source:Copyright of this article belongs to The Royal Society of Chemistry
ID Code:121958
Deposited On:23 Jul 2021 10:18
Last Modified:23 Jul 2021 10:18

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