Deb, Indubhusan ; Dadwal, Mamta ; Mobin, Shaikh M. ; Namboothiri, Irishi N. N. (2006) Hydroxyalkylation of Conjugated Nitroalkenes with Activated Nonenolizable Carbonyl Compounds Organic Letters, 8 (6). pp. 1201-1204. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/ol060041l
Related URL: http://dx.doi.org/10.1021/ol060041l
Abstract
The Morita-Baylis-Hillman reaction of a variety of conjugated nitroalkenes with activated nonenolizable carbonyl compounds such as glyoxylate, trifluoropyruvate, pyruvaldehyde, and ninhydrin in the presence of 40-100 mol % of DMAP in acetonitrile or 100 mol % of imidazole in CHCl3 or THF provided the adducts in decent to good yields. In most cases, the reactions catalyzed by DMAP in acetonitrile were faster and provided the desired MBH adducts in higher yields as compared to the imidazole catalyzed reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 121592 |
| Deposited On: | 19 Jul 2021 11:15 |
| Last Modified: | 19 Jul 2021 11:15 |
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