Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80

Stevenson, Steven ; Phillips, J. Paige ; Reid, Jon E. ; Olmstead, Marilyn M. ; Rath, Sankar Prasad ; Balch, Alan L. (2004) Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80 Chemical Communications (24). p. 2814. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/B412338G

Related URL: http://dx.doi.org/10.1039/B412338G

Abstract

The X-ray crystal structure of Gd3N@C80•NiII(OEP)•1.5(benzene) shows that the Gd3N unit within the Ih C80 cage is pyramidal, whereas Sc3N@C80, Sc3N@C78, Sc3N@C68, Lu3N@C80 and Sc2ErN@C80 have planar M3N units.

Item Type:Article
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ID Code:120933
Deposited On:07 Jul 2021 07:31
Last Modified:07 Jul 2021 07:31

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