Step-wise induction, amplification and inversion of molecular chirality through the coordination of chiral diamines with Zn(ii) bisporphyrin

Ikbal, Sk Asif ; Brahma, Sanfaori ; Rath, Sankar Prasad (2015) Step-wise induction, amplification and inversion of molecular chirality through the coordination of chiral diamines with Zn(ii) bisporphyrin Chemical Communications, 51 (5). pp. 895-898. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/C4CC07955H

Related URL: http://dx.doi.org/10.1039/C4CC07955H

Abstract

For the first time, a clear and unambiguous rationalization of chirality induction, inversion and subsequent amplification process has been demonstrated for the 1 : 1 sandwich and 2 : 3 host–guest supramolecular complexes consisting of Zn(II) host and chiral diamines as guests that has so far remained the most outstanding issue for the chirogenic process.

Item Type:Article
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ID Code:120891
Deposited On:07 Jul 2021 04:55
Last Modified:07 Jul 2021 04:55

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