Khan, Firoz Shah Tuglak ; Shah, Syed Jehanger ; Bhowmik, Susovan ; Reinhard, Fabián G. Cantú ; Sainna, Mala A. ; de Visser, Sam P. ; Rath, Sankar Prasad (2019) Equatorial ligand plane perturbations lead to a spin-state change in an iron(iii) porphyrin dimer Dalton Transactions, 48 (19). pp. 6353-6357. ISSN 1477-9226
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Official URL: http://doi.org/10.1039/C9DT01182J
Related URL: http://dx.doi.org/10.1039/C9DT01182J
Abstract
A complete reversal of the spin state of iron(III) is observed upon a small change to the diporphyrin bridge from ethane to ethene by keeping all other factors intact. Combined analysis using single crystal X-ray structure determination, Mössbauer, variable-temperature magnetic, 1H NMR and EPR studies has confirmed the spin states of iron(III) complexes both in solid and solution phases.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 120828 |
| Deposited On: | 06 Jul 2021 05:45 |
| Last Modified: | 06 Jul 2021 05:45 |
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