Direct organocatalytic hydroalkoxylation of α,β-unsaturated ketones

Ramachary, Dhevalapally B. ; Mondal, Rumpa (2006) Direct organocatalytic hydroalkoxylation of α,β-unsaturated ketones Tetrahedron Letters, 47 (44). pp. 7689-7693. ISSN 0040-4039

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Official URL: http://doi.org/10.1016/j.tetlet.2006.08.134

Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.08.134

Abstract

The direct addition of a variety of alcohols to in situ activated olefins was observed in the presence of mild bifunctional amine/acid catalysts. Unlike existing methods, the reactions proceed at room temperature and in the absence of transition metals. The use of simple commercially available catalysts, amines and acids makes this an attractive method for the preparation of β-alkoxy ketones, which are prevalent targets and intermediates in organic synthesis.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:120788
Deposited On:05 Jul 2021 08:00
Last Modified:05 Jul 2021 08:00

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