Joseph, Jorly ; Ramachary, Dhevalapally B. ; Jemmis, Eluvathingal D. (2006) Electrostatic repulsion as an additional selectivity factor in asymmetric proline catalysis Organic and Biomolecular Chemistry, 4 (14). p. 2685. ISSN 1477-0520
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Official URL: http://doi.org/10.1039/B606996G
Related URL: http://dx.doi.org/10.1039/B606996G
Abstract
The metal free, single amino acid-catalyzed asymmetric desymmetrization (ADS) of meso-compounds 1 with nitrosobenzene 2 has been investigated using DFT. In this communication, we describe the role of electrostatic and dipole–dipole interactions in amino acid-catalyzed reactions, which has not previously been invoked in discussions of these important reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
| ID Code: | 120787 |
| Deposited On: | 05 Jul 2021 07:58 |
| Last Modified: | 05 Jul 2021 07:58 |
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