Ramachary, Dhevalapally B. ; Ramakumar, Kinthada (2011) Direct Organocatalytic Asymmetric Approach to Baylis-Hillman-Type Products Through a Push-Pull Dienamine Platform European Journal of Organic Chemistry, 2011 (14). pp. 2599-2605. ISSN 1434-193X
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Official URL: http://doi.org/10.1002/ejoc.201100075
Related URL: http://dx.doi.org/10.1002/ejoc.201100075
Abstract
A general process for the asymmetric synthesis of 3-alkyl-Hagemann's esters was achieved for the first time through organocatalytic Baylis–Hillman-type (BH-type) reaction of Hagemann's esters with β-nitrostyrenes in the presence of a catalyticamount of L-(3,5-Me2)2DPP/thiourea. The chiral BH-type products were discovered by utilizing the push–pull dienamine platform.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 120759 |
| Deposited On: | 05 Jul 2021 05:13 |
| Last Modified: | 05 Jul 2021 05:13 |
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