Shashank, Adluri B. ; Karthik, S. ; Madhavachary, R. ; Ramachary, Dhevalapally B. (2014) An Enolate-Mediated Organocatalytic Azide-Ketone [3+2]-Cycloaddition Reaction: Regioselective High-Yielding Synthesis of Fully Decorated 1,2,3-Triazoles Chemistry - A European Journal, 20 (51). pp. 16877-16881. ISSN 0947-6539
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Official URL: http://doi.org/10.1002/chem.201405501
Related URL: http://dx.doi.org/10.1002/chem.201405501
Abstract
An enolate-mediated organocatalytic azide–ketone [3+2]-cycloaddition (OrgAKC) reaction of a variety of enolizable arylacetones and deoxybenzoins with aryl azides was developed for the synthesis of fully decorated 1,4-diaryl-5-methyl(alkyl)-1,2,3-triazoles in excellent yields with high regioselectivity at 25 °C for 0.5–6 h. This reaction has an excellent outcome with reference to reaction rate, yield, regioselectivity, operation simplicity, and availability of substrates and catalyst. This reaction has advantages over the previously known metal-mediated reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 120672 |
| Deposited On: | 03 Jul 2021 07:47 |
| Last Modified: | 03 Jul 2021 07:47 |
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