Muthyala, Ramaiah ; Ramachary, Dhevalapally B. ; Mondal, Rumpa ; Jain, Sangeeta (2015) Direct organocatalytic Wittig/Hetero-Diels-Alder reactions in one-pot: synthesis of highly-substituted tetrahydropyranones Arkivoc, 2016 (2). pp. 98-115. ISSN 1551-7012
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Official URL: http://doi.org/10.3998/ark.5550190.p009.252
Related URL: http://dx.doi.org/10.3998/ark.5550190.p009.252
Abstract
A practical and environmentally friendly organocatalytic one-pot strategy designed to furnish the hetero-Diels-Alder products was shown to be effective in the preparation of disubstituted tetrahydropyranones in a highly selective manner. (S)-1-(2-pyrrolidinylmethyl)pyrrolidine catalyzed an asymmetric assembly reaction involving a hetero-Diels-Alder reaction between alkylidene- and arylidene-acetones generated in situ from Wittig reactions with diethyl ketomalonate to furnish the substituted tetrahydropyranones in moderate to very good yields with moderate enantioselectivity
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Arkat USA Inc. |
| ID Code: | 120651 |
| Deposited On: | 03 Jul 2021 06:18 |
| Last Modified: | 03 Jul 2021 06:18 |
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