Anif Pasha, Mohammed ; Peraka, Swamy ; Ramachary, Dhevalapally B. (2021) Catalytic Asymmetric Synthesis of Benzobicyclo[3.2.1]octanes Chemistry - A European Journal . ISSN 0947-6539
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Official URL: http://doi.org/10.1002/chem.202100985
Related URL: http://dx.doi.org/10.1002/chem.202100985
Abstract
Lawsone aldehydes were directly transformed into the biologically important, unique carbon skeleton of chiral methanobenzo[f]azulenes/methanodibenzo[a,d][7]annulenes in high dr and ee and in very good yields by using quinine-thiourea-catalyzed tandem Wittig/intramolecular Michael/intramolecular aldol reactions. This asymmetric catalytic tandem protocol will be highly useful because these final molecules are basic skeletons of important antibiotics.
Item Type: | Article |
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Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
ID Code: | 120627 |
Deposited On: | 02 Jul 2021 08:25 |
Last Modified: | 02 Jul 2021 08:25 |
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