Absolute photoluminescence quantum yield enhancement of poly(2-methoxy 5-[2′-ethylhexyloxy]-p-phenylenevinylene)

Marchioni, F. ; Chiechi, R. ; Patil, S. ; Wudl, F. ; Chen, Y. ; Shinar, J. (2006) Absolute photoluminescence quantum yield enhancement of poly(2-methoxy 5-[2′-ethylhexyloxy]-p-phenylenevinylene) Applied Physics Letters, 89 (6). 061101. ISSN 0003-6951

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Official URL: http://doi.org/10.1063/1.2335365

Related URL: http://dx.doi.org/10.1063/1.2335365

Abstract

A twofold absolute photoluminescence quantum yield (PLQY) enhancement of poly(2-methoxy 5-[2′-ethylhexyloxy]-p-phenylenevinylene) (MEH-PPV) is demonstrated by simple preparation of films where the polymer is blended with the small organic molecule 7,8,10-triphenylfluoranthene (3PF). The photophysical investigation of this particular energy transfer process was carried out using steady state absorption/luminescence spectroscopy and optically detected magnetic resonance techniques. The enhanced PLQY is attributed to direct sensitization of the intrachain emitting state of MEH-PPV by energy transfer from 3PF.

Item Type:Article
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