A new class of organosilicon(IV) compounds based upon tetradentate (N2O2) chelating ligand

Singh, M.S. ; Singh, P.K. (2000) A new class of organosilicon(IV) compounds based upon tetradentate (N2O2) chelating ligand Main Group Metal Chemistry, 23 (3). pp. 183-188. ISSN 0792-1241

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Official URL: http://doi.org/10.1515/MGMC.2000.23.3.183

Related URL: http://dx.doi.org/10.1515/MGMC.2000.23.3.183

Abstract

Complexes of tri-, di- and mono-organosilicon(IV) chlorides with the Schiff base N,N'- ethylenebis (salicylideneimine) have been prepared and characterized by elemental analyses and spectroscopic (IR,1Ή , 13C and 29Si NMR) studies. Molecular weight determination in chloroform reveals the monomeric nature of these complexes. These data support the binding of oxygen to silicon(lV) with an octahedral geometry.

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