Mondal, Kartik Chandra ; Mukherjee, Partha Sarathi (2007) An Antiferromagnetic Mn(II)‐Azido Chain: Synthesis and Characterization Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 37 (9). pp. 735-739. ISSN 1553-3174
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Official URL: http://doi.org/10.1080/15533170701675147
Related URL: http://dx.doi.org/10.1080/15533170701675147
Abstract
A new polymeric compound, [Mn(N3)2(1)2]n (2) where 1=N(phenyl)isonicotinamide (NPI), has been synthesized and characterized by X‐ray crystallography and low‐temperature magnetic study. Compound 2 consists of a one‐dimensional chain of octahedral Mn(II) bridged by azide anions in end‐to‐end fashion. In this compound, the Mn(II) ions are linked by 4 azide bridging ligands and 2 monodentate ligands 1. Variable temperature magnetic susceptibility measurements in the temperature range 300–4 K reveal the existence of weak antiferromagnetic interactions (J=−14.6 cm−1).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Informa UK Limited. |
| Keywords: | Antiferromagnetic; Maganese; (II)1‐D; Chainazido. |
| ID Code: | 120001 |
| Deposited On: | 21 Jun 2021 11:52 |
| Last Modified: | 21 Jun 2021 11:52 |
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