Pathigoolla, Atchutarao ; Gonnade, Rajesh G. ; Sureshan, Kana M. (2012) Topochemical Click Reaction: Spontaneous Self-Stitching of a Monosaccharide to Linear Oligomers through Lattice-Controlled Azide-Alkyne Cycloaddition Angewandte Chemie International Edition, 51 (18). pp. 4362-4366. ISSN 1433-7851
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Official URL: http://doi.org/10.1002/anie.201201023
Related URL: http://dx.doi.org/10.1002/anie.201201023
Abstract
A topochemical click reaction that dispenses with catalyst, solvent, or other modes of activation takes place in crystals of a sugar derivative. The spontaneous, regiospecific azide–alkyne cycloaddition gives linear polymers that are difficult to synthesize by conventional solution-state chemistry (see picture).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 119878 |
| Deposited On: | 18 Jun 2021 05:31 |
| Last Modified: | 18 Jun 2021 05:31 |
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