Sureshan, Kana M. ; Uchimaru, Tadafumi ; Yao, Yonghui ; Watanabe, Yutaka (2008) Strength from weakness: CH⋯π stabilized conformational tuning of benzyl ethers and a consequent co-operative edge-to-face CH⋯π network CrystEngComm, 10 (5). p. 493. ISSN 1466-8033
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Official URL: http://doi.org/10.1039/B718099C
Related URL: http://dx.doi.org/10.1039/B718099C
Abstract
While one of the benzyl ethers of (±)-3,6-di-O-benzyl-1,2-O-isopropylidene-allo-inositol adopts a gauche conformation stabilized by strong intramolecular CH⋯π interactions, the other adopts the anti conformation stabilized by intermolecular CH⋯π interactions in the crystal and this simultaneous action of both intra- and intermolecular CH⋯π interactions manifests an interesting co-operative edge-to-face CH⋯π network
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 119866 |
| Deposited On: | 17 Jun 2021 13:52 |
| Last Modified: | 17 Jun 2021 13:52 |
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