A CONVENIENT AND NOVEL ONE-POT SYNTHESIS OF 3-OXO-P-1,5,3-DIAZAPHOSPHEPINES AND 3- THIOXO-P-1,5,3-DIAZAPHOSPHEPINES

Singh, M. S. ; Rao, R. J. (1992) A CONVENIENT AND NOVEL ONE-POT SYNTHESIS OF 3-OXO-P-1,5,3-DIAZAPHOSPHEPINES AND 3- THIOXO-P-1,5,3-DIAZAPHOSPHEPINES Phosphorus, Sulfur, and Silicon and the Related Elements, 68 (1-4). pp. 115-118. ISSN 1042-6507

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Official URL: http://doi.org/10.1080/10426509208038378

Related URL: http://dx.doi.org/10.1080/10426509208038378

Abstract

In a convenient one-pot sequence, treatment of benzil-dibenzylimine with sodium in dry tetrahydrofuran followed by addition of phosphorodichloridate and phosphorothiodichloridate yields 3-oxo-P-1,5,3-diazaphosphepines and 3-thioxo-P-1,5,3-diazaphosphepines, respectively.

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