NOVEL AND EFFICIENT ONE-POT SYNTHESIS OF PHOSPHORUS HETEROCYCLES CONTAINING THE BICYCLO [2.2.1] HEPTENE MOIETY

Singh, M. S. (1995) NOVEL AND EFFICIENT ONE-POT SYNTHESIS OF PHOSPHORUS HETEROCYCLES CONTAINING THE BICYCLO [2.2.1] HEPTENE MOIETY Phosphorus, Sulfur, and Silicon and the Related Elements, 106 (1-4). pp. 187-191. ISSN 1042-6507

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Official URL: http://doi.org/10.1080/10426509508027906

Related URL: http://dx.doi.org/10.1080/10426509508027906

Abstract

In a convenient one-pot sequence, treatment of camphorquinone with sodium in dry tetrahydrofuran followed by addition of phosphorodichloridate and phosphorothiodichloridate yields 2-oxo-1,3,2-dioxaphospholes and 2-thioxo-1,3,2-dioxaphospholes, respectively. Similar treatment of 3-phenyliminobornan-2-one with sodium in dry THF followed by addition of phosphorodichloridate and phosphorothiodichloridate yields 2-oxo-1,3,2-oxazaphospholes and 2-thioxo-1,3,2-oxazaphospholes.

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