SYNTHESIS AND SPECTROSCOPIC STUDIES OF 2-(N-SALICYLIDENE)-5-CHLOROBENZOPHENONE DERIVATIVES OF ORGANOSILICON(IV)

Singh, M. S. ; Tripathi, U. N. ; Raju, M. David (1997) SYNTHESIS AND SPECTROSCOPIC STUDIES OF 2-(N-SALICYLIDENE)-5-CHLOROBENZOPHENONE DERIVATIVES OF ORGANOSILICON(IV) Phosphorus, Sulfur, and Silicon and the Related Elements, 130 (1). pp. 147-153. ISSN 1042-6507

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Official URL: http://doi.org/10.1080/10426509708033705

Related URL: http://dx.doi.org/10.1080/10426509708033705

Abstract

A few tri-, di- and monorganosilicon(IV) derivatives of Schiff base, 2-(N-salicylidene)-5-chlorobenzophenone have been synthesised by the reactions of the corresponding tri-, di- and monorganosilicon(IV) chlorides with sodium salt of 2-(N-salicylidene)-5-chlorobenzophenone (prepared in siru) in different molar ratios. These newly synthesised derivatives have been characterised by elemental analyses, molecular weights, conductivity measurements and spectral (IR and PMR) studies and their coordination behaviour has been systematically discussed.

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