A Facile Synthetic Approach to Cyclic Carbonates and Thiocarbonates via Dianion Cyclization.

Singh, M. S. ; Singh, B. K. ; Singh, A. K. (2010) A Facile Synthetic Approach to Cyclic Carbonates and Thiocarbonates via Dianion Cyclization. ChemInform, 33 (43). no-no. ISSN 0931-7597

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Official URL: http://doi.org/10.1002/chin.200243208

Related URL: http://dx.doi.org/10.1002/chin.200243208

Abstract

A new strategy for seven-membered nitrogen containing cyclic carbonates and thionocarbonates has been developed. 5,6-Diaryl-1,3,4,7-dioxadiazopin-2-ones 3a-d and -2-thiones 4a-d are prepared in one-pot from vicinal dioximes 1a-d and ethyl chloroformate or carbon disulfide, respectively in good yields via dianion intermediates 2a-d.

Item Type:Article
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Deposited On:16 Jun 2021 11:59
Last Modified:16 Jun 2021 11:59

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