Synthesis of New Benzosubstituted Dioxaphosphonines Containing Quinoxaline Subunit

Singh, Pallavi ; Tripathi, Rakesh ; Verma, Rajiv K. ; Nandi, Ganesh C. ; Gupta, Ashutosh ; Singh, Maya S. (2010) Synthesis of New Benzosubstituted Dioxaphosphonines Containing Quinoxaline Subunit Phosphorus, Sulfur, and Silicon and the Related Elements, 185 (10). pp. 2142-2151. ISSN 1042-6507

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Official URL: http://doi.org/10.1080/10426500903530891

Related URL: http://dx.doi.org/10.1080/10426500903530891

Abstract

A simple and efficient synthesis of previously unknown benzosubstituted dioxaphosphonines containing a quinoxaline subunit is described. Reasonably good yields of the products, mild reaction conditions, and convenient work-up are the advantages of this method. The procedure does not require any catalyst or activator and can be efficiently achieved via dianion cyclization. All the synthesized compounds have been characterized by satisfactory elemental analyses and spectral (IR, 1H, 13C, 31P NMR, and mass) studies.

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