Mukherjee, Partha Sarathi ; Das, Neeladri ; Kryschenko, Yury K. ; Arif, Atta M. ; Stang, Peter J. (2004) Design, Synthesis, and Crystallographic Studies of Neutral Platinum-Based Macrocycles Formed via Self-Assembly Journal of the American Chemical Society, 126 (8). pp. 2464-2473. ISSN 0002-7863
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Official URL: http://doi.org/10.1021/ja039235b
Related URL: http://dx.doi.org/10.1021/ja039235b
Abstract
A series of neutral, platinum-based macrocycles was synthesized from rigid oxygen donor building blocks via self-assembly. The combination of a platinum-based 60° acceptor unit 1 with several linear and angular dicarboxylate bridging ligands afforded hitherto unknown neutral platinum-based supramolecular triangles and rhomboids. In addition, a similar reaction of the diplatinum molecular clip 6 and three different linear dicarboxylates led to the formation of neutral molecular rectangles. Most of the macrocycles were characterized by X-ray single-crystal structure analysis, and, in all cases, NMR spectra were consistent with the formation of single highly symmetrical species.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 119415 |
| Deposited On: | 12 Jun 2021 16:29 |
| Last Modified: | 12 Jun 2021 16:29 |
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