Ghosh, Sushobhan ; Mukherjee, Partha Sarathi (2007) Self-Assembly of Metallamacrocycles via a Rigid Phosphorus Donor Linker# Organometallics, 26 (14). pp. 3362-3367. ISSN 0276-7333
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Official URL: http://doi.org/10.1021/om700296k
Related URL: http://dx.doi.org/10.1021/om700296k
Abstract
The coordination-driven self-assembly of a series of discrete 2D metallomacrocycles from a rigid diphosphine donor linker and Pd/Pt-containing 90° acceptors is described. All these assemblies are characterized by multinuclear NMR and, in four cases, X-ray crystallography. The selective formation of a diphosphine bridged macrocycle, [(en)Pd(μ-trans-PPh2CHCHPPh2)2Pd(en)]4+, from a 1:1:1 mixture of cis-Pd(en)(NO3)2, trans-Ph2PCHCHPPh2, and 1,2-bis(4-pyridyl)ethane is also established.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 119358 |
| Deposited On: | 11 Jun 2021 04:50 |
| Last Modified: | 11 Jun 2021 04:50 |
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