Pillar height dependent formation of unprecedented Pd8 molecular swing and Pd6 molecular boat via multicomponent self-assembly

Samanta, Dipak ; Shanmugaraju, Sankarasekaran ; Joshi, Sachin A. ; Patil, Yogesh P. ; Nethaji, Munirathinam ; Mukherjee, Partha Sarathi (2012) Pillar height dependent formation of unprecedented Pd8 molecular swing and Pd6 molecular boat via multicomponent self-assembly Chemical Communications, 48 (17). p. 2298. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/C2CC16345D

Related URL: http://dx.doi.org/10.1039/C2CC16345D

Abstract

Three-component self-assembly of a cis-blocked 90° Pd(II) acceptor with a mixture of a tetraimidazole and a linear dipyridyl donor self-discriminated into unusual Pd8 molecular swing (1) and Pd6 molecular boat (2), which are characterized by single-crystal X-ray diffraction analysis; their ability to bind C60 in solution is established by fluorescence titration.

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