Samanta, Dipak ; Mukherjee, Sandip ; Patil, Yogesh P. ; Mukherjee, Partha Sarathi (2012) Self-Assembled Pd6Open Cage with Triimidazole Walls and the Use of Its Confined Nanospace for Catalytic Knoevenagel- and Diels-Alder Reactions in Aqueous Medium Chemistry - A European Journal, 18 (39). pp. 12322-12329. ISSN 0947-6539
Full text not available from this repository.
Official URL: http://doi.org/10.1002/chem.201201679
Related URL: http://dx.doi.org/10.1002/chem.201201679
Abstract
The two-component self-assembly of a 90° PdII acceptor and a triimidazole donor led to the formation of a water-soluble semi-cylindrical cage with a hydrophobic cavity, which was separately crystallized with hydrophilic- and hydrophobic guests. The parent cage was found to catalyze the Knoevenagel condensation reaction of a series of aromatic mono-aldehydes with active methylene compounds, such as Meldrum′s acid or 1,3-dimethylbarbituric acid. The confined hydrophobic nanospace within this cage was also used in the catalytic Diels–Alder reactions of 9-hydroxymethylanthracene with N-phenylmaleimide or N-cyclohexylmaleimide.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 118781 |
| Deposited On: | 29 May 2021 18:38 |
| Last Modified: | 29 May 2021 18:38 |
Repository Staff Only: item control page
